International Chemical Safety Cards

TRI-ALLATE ICSC: 0201

TRI-ALLATE
S-(2,3,3-Trichloroallyl) diisopropylthiocarbamate
S-(2,3,3-Trichloro-2-propenyl) bis(1-methylethyl)carbamothioate
C10H16Cl3NOS / ((CH3)2CH)2NCOSCH2CCl=CCl2
Molecular mass: 304.7
CAS # 2303-17-5
RTECS # EZ8575000
ICSC # 0201
UN # 2757
EC # 006-039-00-X
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible under specific conditions. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST! PREVENT GENERATION OF MISTS! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!

  • INHALATION

    		• Local exhaust.
    		Fresh air, rest. Refer for medical attention.
  • SKIN
    		• Redness.
    		Protective gloves.
    		Remove contaminated clothes. Rinse skin with plenty of water or shower.
  • EYES
    		• Redness.
    		Safety spectacles.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION

    		• Do not eat, drink, or smoke during work. Wash hands before eating.
    		Rinse mouth. Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer (extra personal protection: A/P2 filter respirator for organic vapour and harmful dust).
    		Separated from strong bases, strong acids, food and feedstuffs. Dry. Keep in a well-ventilated room.
    		Do not transport with food and feedstuffs.
    Xn symbol
    R: 22
    S: (2)
    UN Hazard Class: 6.1
    UN Packing Group: III
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0201 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    TRI-ALLATE ICSC: 0201

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    PHYSICAL STATE; APPEARANCE:
     OR CLEAR LIQUID. COLOURLESS CRYSTALS

    PHYSICAL DANGERS:

    CHEMICAL DANGERS:
     The substance decomposes on heating above 200°C or on burning producing toxic and corrosive gases including hydrogen chloride, nitrogen oxides and sulfur oxides.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV not established.


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

    INHALATION RISK:
     No indication can be given about the rate in which a harmful concentration of airborne particles is reached on dispersing this substance.

    EFFECTS OF SHORT-TERM EXPOSURE:
     The substance irritates the eyes and the skin.


    PHYSICAL
    PROPERTIES
    Boiling point at 0.04 kPa: 117°C
    Melting point: 29-30°C
    Relative density (water = 1): 1.27
    Solubility in water: none
    		Vapour pressure, Pa at 25°C: 0.016
    Flash point: 90°C c.c.
    Octanol/water partition coefficient as log Pow: 3.98 (calculated)
    ENVIRONMENTAL
    DATA
         		The substance is toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.
    N O T E S
    Technical Tri-allate is an oily amber liquid. If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Ovadex BW, Dipthal and Far-Go are trade names.
    Transport Emergency Card: TEC (R)-61G47c
    ADDITIONAL INFORMATION


    ICSC: 0201 TRI-ALLATE
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.