International Chemical Safety Cards

d-ALLETHRIN ICSC: 0213

d-ALLETHRIN
(RS)-3-Allyl-2-methyl-4-oxocyclopent-2-enyl (1R)-cis-trans-chrysanthemate
2-Methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate
C19H26O3
Molecular mass: 302.4
CAS # 584-79-2
RTECS # GZ1925000
ICSC # 0213
UN # 2902
EC # 006-025-00-3
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. See Notes.
NO open flames.
Powder, AFFF, foam, carbon dioxide.
EXPLOSION

In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
PREVENT GENERATION OF MISTS!

  • INHALATION
    		• Cough.
    		Ventilation, local exhaust, or breathing protection.
    		Fresh air, rest. Refer for medical attention.
  • SKIN
    		• Redness.
    		Protective gloves.
    		Remove contaminated clothes. Rinse and then wash skin with water and soap.
  • EYES
    		• Redness.
    		Safety goggles.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION

    		• Do not eat, drink, or smoke during work. Wash hands before eating.
    		Rinse mouth. Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Collect leaking and spilled liquid in sealable containers as far as possible. Treat remaining liquid with alkali. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer (extra personal protection: P2 filter respirator for harmful particles).
    		Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs, alkalies. Keep in the dark. Keep in a well-ventilated room.
    		Do not transport with food and feedstuffs.
    Xn symbol
    R: 22
    S: (2-)36
    UN Hazard Class: 6.1
    UN Pack Group: III
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0213 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    d-ALLETHRIN ICSC: 0213

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    PHYSICAL STATE; APPEARANCE:
     OILY LIQUID.

    PHYSICAL DANGERS:

    CHEMICAL DANGERS:
     The substance decomposes on heating above 400°C. Incompatible with alkalies.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV not established.
    PDK not established.


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

    INHALATION RISK:
     No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

    EFFECTS OF SHORT-TERM EXPOSURE:
     The substance irritates the eyes, the skin and the respiratory tract. The substance may cause effects on the nervous system.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
    PHYSICAL
    PROPERTIES
    Relative density (water = 1): 1.01
    Solubility in water: none
    		 Flash point: 130°C
    ENVIRONMENTAL
    DATA
         		This substance may be hazardous to the environment; special attention should be given to fish and honey bees.
    N O T E S
    Some liquid formulations may be highly flammable and/or explosive. Carrier solvents used in commercial formulations may change physical and toxicological properties. Pynamin Forte is a trade name. Also consult publication Health and Safety Guide No. 24 Allethrins, and Environmental Health Criteria No. 87 Allethrins, of IPCS. Also consult ICSC # 0228, 0212, 0227.
    ADDITIONAL INFORMATION


    ICSC: 0213 d-ALLETHRIN
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.