International Chemical Safety Cards

CARBON TETRABROMIDE ICSC: 0474

CARBON TETRABROMIDE
Tetrabromomethane
CBr4
Molecular mass: 331.63
CAS # 558-13-4
RTECS # FG4725000
ICSC # 0474
UN # 2516
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST! STRICT HYGIENE!

  • INHALATION
    		• Sore throat. Cough. Laboured breathing. Dullness. Drowsiness. Symptoms may be delayed (see Notes).
    		Local exhaust or breathing protection.
    		Fresh air, rest. Half-upright position. Refer for medical attention.
  • SKIN
    		• Redness. Pain. Serious skin burns.
    		Protective gloves. Protective clothing.
    		Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.
  • EYES
    		• Redness. Pain. Blurred vision.
    		Face shield, or eye protection in combination with breathing protection.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION
    		• Sore throat. Abdominal pain. Diarrhoea. Dullness.
    		Do not eat, drink, or smoke during work.
    		Rinse mouth. Give plenty of water to drink. Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Sweep spilled substance into containers. Carefully collect remainder, then remove to safe place (extra personal protection: P2 filter respirator for harmful particles).
    		Separated from food and feedstuffs.
    		Do not transport with food and feedstuffs.
    UN Hazard Class: 6.1
    UN Packing Group: III
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0474 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    CARBON TETRABROMIDE ICSC: 0474

    I
    M
    P
    O
    R
    T
    A
    N
    T

    D
    A
    T
    A
    PHYSICAL STATE; APPEARANCE:
     COLOURLESS CRYSTALS.

    PHYSICAL DANGERS:

    CHEMICAL DANGERS:
     The substance decomposes in a flame or on a hot surface, forming toxic gases (bromine). Explodes on impact when mixed with lithium.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV: 0.1 ppm; 1.4 mg/m3 (as TWA); 0.3 ppm; 4.1 mg/m3 (as STEL) (ACGIH 1991-1992).
    OSHA PEL: none
    NIOSH REL: TWA 0.1 ppm (1.4 mg/m3) ST 0.3 ppm (4 mg/m3)
    NIOSH IDLH: No data


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation and by ingestion.

    INHALATION RISK:
     Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly by dispersing.

    EFFECTS OF SHORT-TERM EXPOSURE:
     The substance is corrosive to the eyes, the skin and the respiratory tract. The substance may cause effects on the nervous system, liver, and kidneys. Exposure to high concentrations may result in unconsciousness.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
     The substance may have effects on the liver.
    PHYSICAL
    PROPERTIES
    Boiling point: 190°C
    Melting point: 90°C
    Relative density (water = 1): 3.42
    		 Solubility in water: none
    Vapour pressure, kPa at 96°C: 5.33
    Relative vapour density (air = 1): 11.4
    ENVIRONMENTAL
    DATA
    NOTES
    The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered. Do NOT use in the vicinity of a fire or a hot surface, or during welding.
    Transport Emergency Card: TEC (R)-61G11c
    ADDITIONAL INFORMATION


    ICSC: 0474 CARBON TETRABROMIDE
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.