International Chemical Safety Cards

FENAMIPHOS ICSC: 0483

FENAMIPHOS
Phenamiphos
Ethyl-3-methyl-4-(methylthio)phenyl(1-methylethyl)phosphoramidate
C13H22NO3PS
Molecular mass: 303.4
CAS # 22224-92-6
RTECS # TB3675000
ICSC # 0483
UN # 2783
EC # 015-123-00-5
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible.
NO open flames.
Powder, AFFF, foam, carbon dioxide.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST! STRICT HYGIENE!
IN ALL CASES CONSULT A DOCTOR!
  • INHALATION
    		• Profuse sweating, slow heartbeat, Abdominal cramps. Diarrhoea. Dizziness. Headache. Laboured breathing. Nausea. Vomiting. Weakness. Wheezing. pupillary constriction, muscle cramps. Symptoms may be delayed (see Notes).
    		Local exhaust or breathing protection.
    		Fresh air, rest. Artificial respiration if indicated. Refer for medical attention.
  • SKIN
    		• MAY BE ABSORBED! Redness. Roughness. (see Inhalation).
    		Protective gloves. Protective clothing.
    		Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
  • EYES
    		• Blurred vision. (further see Inhalation).
    		face shield, or eye protection in combination with breathing protection.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION
    		• Abdominal cramps. Diarrhoea. Laboured breathing. Nausea. Vomiting. (see Inhalation).
    		Do not eat, drink, or smoke during work.
    		Rinse mouth. Give a slurry of activated charcoal in water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. (extra personal protection: P3 filter respirator for toxic particles).
    		Separated from alkalis. Dry. Well closed.

    T symbol
    T+ symbol
    R: 24-28
    S: 23-28-36/37-45
    UN Hazard Class: 6.1
    UN Packing Group: I
    marine pollutant.
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0483 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    FENAMIPHOS ICSC: 0483

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    PHYSICAL STATE; APPEARANCE:
     WHITE TO TAN SOLID (technical grade) and Colourless crystals (pure) , WITH CHARACTERISTIC ODOUR.

    PHYSICAL DANGERS:

    CHEMICAL DANGERS:
     On combustion, forms toxic gases and fumes (carbon monoxide ICSC # 0023, and oxides of nitrogen, phosphorous, and sulphur).

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV: ppm; 0.1 mg/m3 (as TWA) (skin) (ACGIH 1996).
    OSHA PEL: none
    NIOSH REL: TWA 0.1 mg/m3 skin
    NIOSH IDLH: No data


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation and through the skin and by ingestion.

    INHALATION RISK:
     Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

    EFFECTS OF SHORT-TERM EXPOSURE:
     Exposure could cause lowering of consciousness. Exposure may result in death.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
    PHYSICAL
    PROPERTIES
    Melting point: 49.2°C
    Solubility in water, g/100 ml: 0.03
    		 Vapour pressure, Pa at 30°C: <1
    ENVIRONMENTAL
    DATA
    N O T E S
    Formulation types: Emulsifiable concentrate; granules. Also in mixed formulations with Isofenphos. Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home. B 68138, Bay 68138, Bayer 68138, Bay SRA 3886, ENT 27572, Nemacur, Nemacur P, and NSC 195106 are trade names.
    Transport Emergency Card: TEC (R)-756b (Pesticides (solid), (toxic or harmful organic phosphorous compounds) (with UN # 2588)
    ADDITIONAL INFORMATION


    ICSC: 0483 FENAMIPHOS
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.