International Chemical Safety Cards

THIOACETIC ACID ICSC: 0679

THIOACETIC ACID
Ethanethioic acid
Thiacetic acid
C2H4OS/CH3COSH
Molecular mass: 76.12
CAS # 507-09-5
RTECS # AJ5600000
ICSC # 0679
UN # 2436
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames, NO sparks, and NO smoking.
Powder, alcohol-resistant foam, water spray, carbon dioxide.
EXPLOSION Vapour/air mixtures are explosive.
Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
STRICT HYGIENE!

  • INHALATION
    		• Cough. Laboured breathing. Nausea. Sore throat. Symptoms may be delayed (see Notes).
    		Ventilation, local exhaust, or breathing protection.
    		Fresh air, rest. Half-upright position. Artificial respiration if indicated. Refer for medical attention.
  • SKIN
    		• Burning sensation. Pain.
    		Protective gloves. Protective clothing.
    		Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention. Wear protective gloves when administering first aid.
  • EYES
    		• Redness. Pain. Severe deep burns.
    		Safety goggles or eye protection in combination with breathing protection.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION
    		• Abdominal cramps. Burning sensation (further see Inhalation).
    		Do not eat, drink, or smoke during work.
    		Rinse mouth. Do NOT induce vomiting. Give nothing to drink. Rest. Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Evacuate danger area! Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. Do NOT absorb in saw-dust or other combustible absorbents. NEVER direct water jet on liquid (extra personal protection: complete protective clothing including self-contained breathing apparatus).
    		Fireproof. Separated from strong oxidants, strong bases. Keep tightly closed. Cool. Dry.
    		Airtight.
    UN Hazard Class: 3
    UN Packing Group: II
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0679 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    THIOACETIC ACID ICSC: 0679

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    PHYSICAL STATE; APPEARANCE:
     YELLOW FUMING LIQUID , WITH PUNGENT ODOUR.

    PHYSICAL DANGERS:
     The vapour is heavier than air and may travel along the ground; distant ignition possible.

    CHEMICAL DANGERS:
     The substance decomposes on burning producing toxic and corrosive fumes (sulfur oxides). The substance is a medium strong acid and is corrosive. Reacts violently with strong oxidants causing fire and explosion hazard. Reacts slowly with water forming acetic acid and hydrogen sulfide.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV not established.


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation of its vapour and by ingestion.

    INHALATION RISK:
     No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

    EFFECTS OF SHORT-TERM EXPOSURE:
     Corrosive. The substance is corrosive to the eyes, the skin and the respiratory tract. Inhalation of the vapour may cause lung oedema (see Notes). The effects may be delayed. Medical observation is indicated.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
     The substance may have effects on the kidneys.
    PHYSICAL
    PROPERTIES
    Boiling point: 93°C
    Melting point: <-17°C
    Relative density (water = 1): 1.074
    		 Solubility in water: soluble (reacts slowly)
    Relative vapour density (air = 1): 2.62
    Flash point: 18-21°C
    ENVIRONMENTAL
    DATA
    NOTES
    Explosive limits are unknown in literature. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered.
    Transport Emergency Card: TEC (R)-30G34
    ADDITIONAL INFORMATION


    ICSC: 0679 THIOACETIC ACID
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.