International Chemical Safety Cards

FERBAM ICSC: 0792

FERBAM
Ferric dimethyldithiocarbamate
Iron tris(dimethyldithiocarbamate)
C9H18FeN3S6 / ((CH3)2NCS2)3Fe
Molecular mass: 416.5
CAS # 14484-64-1
RTECS # NO8750000
ICSC # 0792
UN # 2771
EC # 006-051-00-5
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Water spray, powder.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST!

  • INHALATION
    		• Cough. Sore throat.
    		Local exhaust or breathing protection.
    		Fresh air, rest. Refer for medical attention.
  • SKIN
    		• Dry skin. Redness. Pain.
    		Protective gloves. Protective clothing.
    		Remove contaminated clothes. Rinse and then wash skin with water and soap.
  • EYES
    		• Redness. Pain.
    		Safety spectacles.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION
    		• Confusion. Drowsiness. Headache. Nausea.
    		Do not eat, drink, or smoke during work. Wash hands before eating.
    		Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. (extra personal protection: P2 filter respirator for harmful particles).
    		Separated from strong oxidants, copper- or mercury-containing compounds and alkaline materials, food and feedstuffs. Dry. Well closed.
    		Do not transport with food and feedstuffs.
    Xi symbol
    R: 36/37/38
    S: (2)
    UN Hazard Class: 6.1
    UN Packing Group: III
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0792 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    FERBAM ICSC: 0792

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    PHYSICAL STATE; APPEARANCE:
     ODOURLESS BLACK CRYSTALLINE POWDER

    PHYSICAL DANGERS:

    CHEMICAL DANGERS:
     The substance decomposes on heating and on contact with moisture producing toxic and flammable gases. Reacts with strong oxidants.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV: 10 mg/m3 A4 (as TWA) (ACGIH 1997).
    MAK: 15 mg/m3; (1996)
    OSHA PEL: TWA 15 mg/m3
    NIOSH REL: TWA 10 mg/m3
    NIOSH IDLH: 800 mg/m3


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

    INHALATION RISK:
     Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.

    EFFECTS OF SHORT-TERM EXPOSURE:
     The substance irritates the eyes, the skin and the respiratory tract. The substance may cause effects on the central nervous system.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
     Repeated or prolonged contact with skin may cause dermatitis. Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the nervous system and thyroid in high doses.
    PHYSICAL
    PROPERTIES
    Melting point (decomposes): 180°C
    		 Solubility in water: none
    ENVIRONMENTAL
    DATA
         		The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.
    N O T E S
    The substance is combustible but no flash point is available in literature. Exposure to ferbam may cause alcohol intolerance. Depending on the degree of exposure, periodic medical examination is indicated. Carrier solvents used in commercial formulations may change physical and toxicological properties. Ferbam is often used in combinations with dithiocarbamates. Ferbeck, Fermate, Ferradow, Hexaferb, Karbam Black, Knockmate and Trifungol are trade names.
    ADDITIONAL INFORMATION


    ICSC: 0792 FERBAM
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.