TYPES OF HAZARD/ EXPOSURE
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ACUTE HAZARDS/ SYMPTOMS
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PREVENTION
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FIRST AID/ FIRE FIGHTING
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FIRE
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Flammable.
Moderate fire hazards in form of dust when exposed to heat or flame.
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NO open flames, NO sparks, and NO smoking.
NO contact with oxidizing agents.
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Foam,
carbon dioxide,
dry powder.
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EXPLOSION
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Finely dispersed particles form explosive mixtures in air.
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Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.
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EXPOSURE
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PREVENT DISPERSION OF DUST!
STRICT HYGIENE!
AVOID EXPOSURE OF (PREGNANT) WOMEN!
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IN ALL CASES CONSULT A DOCTOR!
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INHALATION
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Drowsiness.
Headache.
Garlic odour.
Nausea.
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Local exhaust or breathing protection.
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Fresh air, rest.
Artificial respiration if indicated.
Refer for medical attention.
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SKIN
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MAY BE ABSORBED!
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Protective gloves.
Protective clothing.
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Remove contaminated clothes.
Rinse and then wash skin with water and soap.
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EYES
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Redness.
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Safety goggles
or eye protection in combination with breathing protection if powder.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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INGESTION
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Abdominal pain.
Constipation.
Nausea.
Vomiting.
Garlic odour of the breath
(further see Inhalation).
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Do not eat, drink, or smoke during work.
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Give a slurry of activated charcoal in water to drink.
Refer for medical attention.
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SPILLAGE DISPOSAL
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STORAGE
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PACKAGING & LABELLING
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Sweep spilled substance into sealed containers.
Carefully collect remainder,
then remove to safe place
(extra personal protection: P3 filter respirator for toxic particles).
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Separated from
strong oxidants,
strong bases,
strong acids,
halogens and interhalogens.
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Unbreakable packaging; put breakable packaging into closed unbreakable container.
UN Hazard Class: 6.1
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SEE IMPORTANT INFORMATION ON BACK
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ICSC: 0986
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Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993
No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.
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