International Chemical Safety Cards

TRIPHENYL PHOSPHATE ICSC: 1062

Triphenyl phosphate
Phosphoric acid, triphenyl ester
TPP
(C6H5)3PO4
Molecular mass: 326.3
CAS # 115-86-6
RTECS # TC8400000
ICSC # 1062
TYPES OF
HAZARD/
EXPOSURE
ACUTE HAZARDS/
SYMPTOMS
PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Combustible.
NO open flames.
Powder, water spray, foam, carbon dioxide.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST!

  • INHALATION

  • Local exhaust or breathing protection.
    Fresh air, rest, artificial respiration if indicated, and refer for medical attention.
  • SKIN

  • Protective gloves.
    Remove contaminated clothes, rinse and then wash skin with water and soap, and refer for medical attention if irritation persists.
  • EYES

  • Safety spectacles.
    First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION
  • See Inhalation.
    Do not eat, drink, or smoke during work.
    Rinse mouth and refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Sweep spilled substance into containers, carefully collect remainder, then remove to safe place (extra personal protection: P2 filter respirator for harmful particles).


    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 1062 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1990 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    TRIPHENYL PHOSPHATE ICSC: 1062

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    PHYSICAL STATE; APPEARANCE:
    COLOURLESS, CRYSTALLINE POWDER , WITH CHARACTERISTIC ODOUR.

    PHYSICAL DANGERS:


    CHEMICAL DANGERS:
    Upon heating, toxic fumes are formed.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
    TLV: 3 mg/m3 (as TWA) (ACGIH 1992-1993)
    OSHA PEL: TWA 3 mg/m3
    NIOSH REL: TWA 3 mg/m3
    NIOSH IDLH: 1000 mg/m3


    ROUTES OF EXPOSURE:
    The substance can be absorbed into the body by inhalation and by ingestion.

    INHALATION RISK:
    Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

    EFFECTS OF SHORT-TERM EXPOSURE:


    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
    The substance may have effects on blood enzymes. Exposures to animals have produced muscle weakness and paralysis; these effects have not been reported in humans.
    PHYSICAL
    PROPERTIES
    Boiling point: 370°C
    Melting point: 49-50°C
    Relative density (water = 1): 1.27
    Solubility in water, g/100 ml at 20°C: 0.001
    Vapour pressure, Pa at 20°C: 1
    Flash point: (c.c.) 220°C
    Octanol/water partition coefficient as log Pow: 4.59
    ENVIRONMENTAL
    DATA

    NOTES
    Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
    NFPA Code: H2; F1; R0
    ADDITIONAL INFORMATION


    ICSC: 1062 TRIPHENYL PHOSPHATE
    © IPCS, CEC, 1990
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.