International Chemical Safety Cards

TITANIUM TETRACHLORIDE ICSC: 1230

TITANIUM TETRACHLORIDE
Titanium chloride
Tetrachlorotitanium
TiCl4
Molecular mass: 189.7
CAS # 7550-45-0
RTECS # XR1925000
ICSC # 1230
UN # 1838
EC # 022-001-00-5
TYPES OF
HAZARD/
EXPOSURE 		ACUTE HAZARDS/
SYMPTOMS 		PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: powder, carbon dioxide, NO hydrous agents, NO water.
EXPLOSION

In case of fire: cool drums, etc., by spraying with water but avoid contact of the substance with water.
EXPOSURE
AVOID ALL CONTACT!
IN ALL CASES CONSULT A DOCTOR!
  • INHALATION
    		• Corrosive. Burning sensation. Cough. Laboured breathing. Tightness in the chest. Symptoms may be delayed (see Notes).
    		Ventilation, local exhaust, or breathing protection.
    		Fresh air, rest. Half-upright position. Artificial respiration if indicated. Refer for medical attention.
  • SKIN
    		• Corrosive. Redness. Pain. Blisters.
    		Protective gloves. Protective clothing.
    		Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
  • EYES
    		• Corrosive. Redness. Pain. Severe deep burns. Permanent damage.
    		Face shield or eye protection in combination with breathing protection.
    		First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION
    		• Corrosive. Abdominal cramps. Burning sensation. Shock or collapse.
    		Do not eat, drink, or smoke during work.
    		Rinse mouth. Do NOT induce vomiting. Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Evacuate danger area! Consult an expert! Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. NEVER direct water jet on liquid. Remove with fine water spray (extra personal protection: complete protective clothing including self-contained breathing apparatus).
    		Separated from food and feedstuffs. Dry. Well closed.
    		Do not transport with food and feedstuffs.
    C symbol
    R: 14-34-36/37
    S: (1/2-)7/8-26-45
    UN Hazard Class: 8
    UN Packing Group: II
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 1230 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993 No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and IDLH values.

    International Chemical Safety Cards

    TITANIUM TETRACHLORIDE ICSC: 1230

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    PHYSICAL STATE; APPEARANCE:
     COLOURLESS TO LIGHT YELLOW LIQUID , WITH PUNGENT ODOUR.

    PHYSICAL DANGERS:

    CHEMICAL DANGERS:
     The substance decomposes on heating or on burning producing toxic fumes including hydrogen chloride (see ICSC # 0163). Reacts violently with water releasing heat and corrosive fumes of hydrogen chloride. On contact with air it emits hydrochloric acid. Attacks many metals in presence of water.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
     TLV not established.


    		ROUTES OF EXPOSURE:
     The substance can be absorbed into the body by inhalation of its vapour and by ingestion.

    INHALATION RISK:
     No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

    EFFECTS OF SHORT-TERM EXPOSURE:
     Corrosive. The substance is corrosive to the eyes, the skin and the respiratory tract. Corrosive on ingestion. Inhalation of vapour may cause lung oedema (see Notes). The effects may be delayed. Medical observation is indicated.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
     The substance may have effects on the lungs and respiratory tract , resulting in impaired functions.
    PHYSICAL
    PROPERTIES
    Boiling point: 136.4°C
    Melting point: -24.1°C
    Relative density (water = 1): 1.7
    		 Solubility in water: reaction
    Vapour pressure, kPa at 21.3°C: 1.3
    Relative vapour density (air = 1): 6.5
    ENVIRONMENTAL
    DATA
    N O T E S
    Reacts violently with fire extinguishing agents such as water. Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered.
    Transport Emergency Card: TEC (R)-733
    NFPA Code: H3; F0; R2; W
    ADDITIONAL INFORMATION


    ICSC: 1230 TITANIUM TETRACHLORIDE
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and IDLH values.